SACHEM\uc740 \ud14c\ud2b8\ub77c\ubd80\ud2f8\uc554\ubaa8\ub284 \ubd88\ud654\ubb3c(TBAF)\uc744 \ub2e4\uc74c \uae30\ub2a5\uc744 \uc81c\uacf5\ud558\ub294 3\uc218\ud654\ubb3c \uacb0\uc815\uccb4\ub85c \uc81c\uacf5\ud569\ub2c8\ub2e4.<\/p>\n
\uc751\uc6a9<\/b> <\/b>\ubd84\uc57c<\/b>:<\/b><\/p>\n TBAF <\/b>\uc0ac\uc6a9<\/b> <\/b>\uac00\ub2a5\ud55c<\/b> <\/b>\uc81c\ud488<\/b>:<\/b><\/p>\n \uc2dc\uc124\uacfc \uc644\ubcbd\ud55c \ubb3c\ub958 \uc9c0\uc6d0\uc758 \uae00\ub85c\ubc8c \ub124\ud2b8\uc6cc\ud06c\ub294 \uc804\uc138\uacc4\u2009\uc5b4\ub514\uc11c\ub098 \uc77c\uad00\uc131 \uc788\uace0 \uc548\uc815\uc801\uc774\uace0 \ub2e4\uc591\ud55c \uc218\ub7c9\uc73c\ub85c TBAF\ub97c \uc9c0\uc6d0\ud560 \uc218 \uc788\uc2b5\ub2c8\ub2e4.<\/p>\n \ubc31\uc11c<\/b>: <\/b> \uc0ac\uc6a9<\/b> <\/b>\uac00\ub2a5\ud55c<\/b> <\/b>\uc81c\ud488<\/b><\/p>\n TBAF(<\/b>\ud14c\ud2b8\ub77c\ubd80\ud2f8\uc554\ubaa8\ub284<\/b> <\/b>\ubd88\ud654\ubb3c<\/b>) 3<\/b>\uc218\ud654\ubb3c<\/b>, 98%<\/b> \ud574\ub2f9 \uc751\uc6a9 \ubd84\uc57c \uc694\uad6c\uc5d0 \ub300\ud574 \ub2f9\uc0ac\uc640 \uc0c1\ub2f4\ud558\uae38 \uc6d0\ud558\uc2ed\ub2c8\uae4c? \ub2f9\uc0ac\uc5d0 \ubb38\uc758\ud558\uc2ed\uc2dc\uc624.<\/a><\/p>\n \ud14c\ud2b8\ub77c\ubd80\ud2f8\uc554\ubaa8\ub284<\/b> <\/b>\ubd88\ud654\ubb3c\uc758<\/b> <\/b>\uc120\ud0dd\ub41c<\/b> <\/b>\uae30\uc0ac<\/b> <\/b>\ubc0f<\/b> <\/b>\ud2b9\ud5c8<\/b><\/b><\/p>\n [toggle_container keep_open=”false” initial_open=””] 1. Adam, M. J.; Jivan, S.; Huser, J. M.; Lu, J. (2000).11C-methylations using 11C-methyl iodide and tetrabutylammonium fluoride<\/a>. Radiochimica Acta (2000), 88(3-4), 207-209.<\/p>\n 2. Bartsch, Richard (1970) .\u00a0Eliminations from 2-butyl halides induced by halide ions in dimethylformamide and dimethyl sulfoxide<\/a>. Journal of Organic Chemistry 35(4), 1023-5.<\/p>\n 3. Crawley, Seth and Funk, Raymond. (2006).\u00a0Generation of Aza-ortho-xylylenes via Ring Opening of 2-(2- Acylaminophenyl)aziridines: Application in the Construction of the Communesin Ring System<\/a>. Organic Letters 8(18), 3995-3998.<\/p>\n 4. Dahlstedt, Emma; Hellberg, Jonas; Petoral, Rodrigo M., Jr.; Uvdal, Kajsa (2004\u00a0Synthesis of tetrathiafulvalenes suitable for self-assembly applications<\/a>. Journal of Materials Chemistry, 14(1), 81-85.<\/p>\n 5. Denmark, Scott E; Pan, Weitao. (2003).\u00a0Intramolecular Syn and Anti Hydrosilylation and Silicon-Assisted Cross-Coupling: Highly Regio- and Stereoselective Synthesis of Trisubstituted Allylic Alcohols<\/a>.Organic Letters 5(7), 1119-1122.<\/p>\n 6. Hojo, Makoto; Ishibashi, Naruyasu; Hosomi, Akira(1994).\u00a0Heteroarylthiomethylsilanes. Synthesis and application to heteroarylthiomethylation of carbonyl compounds<\/a>. Heteroatom Chemistry 5(3), 229-34.<\/p>\n 7. Lyapkalo, Ilya M.; Webel, Matthias; Reissig, Hans-Ulrich (2001).\u00a0Enantioselective synthesis of cyclohexenylalkenes by asymmetric deprotonation of 4-tert-butylcyclohexanone followed by O-nonaflation and Heck couplings<\/a>. Synlett (8), 1293-1295.<\/p>\n 8. Muratam Miki; Ohara, Hiroya; Oiwa, Ryo; Watanabe, Shinji; Masuda,Yuzuru (2006).Palladium(0)-catalyzed silylation of aryl halides with triorganosilanes: synthesis of aryl(2-furyl)silanes.<\/a>\u00a0Synthesis, (11), 1771-1774.<\/p>\n 9. Ogawa, Toshihisa; Hatayama, Katsuo; Maeda, Hiroshi; Kita, Yasuyuki (1994).\u00a0Mild and facile cleavage of 2-cyanoethyl ester using sodium sulfide or tetrabutylammonium fluoride. Synthesis of 1,4-dihydropyridine monocarboxylic acids and unsymmetrical 1,4-dihydropyridine dicarboxylates<\/a>. Chemical Pharmaceutical Bulletin 42(8), 1579-89.<\/p>\n 10. Ozasa, Nobuko; Wadamoto, Manabu; Ishihara, Kazuaki; Yamamoto, Hisashi (2003).Aldol synthesis with an aqueous solution of formalin<\/a>. Synlett (14), 2219-2221.<\/p>\n 11. Robins, Morris J.; Sarker, Sanchita; Samano, Vicente;.Wnuk, Stanislaw F (1997).\u00a0Nucleic acid related compounds. 94. Remarkably high stereoselective reductions of 2\u2032- and 3\u2032-keto nucleosides to give arabino, ribo, and xylofuranosyl nucleosides with hydrogen isotopes at C2\u2032 and C3\u2032<\/a>. Tetrahedron 53(2), 447-456.<\/p>\n 12. Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro (2004).\u00a0Cross-coupling of triallyl(aryl)silanes with aryl bromides and chlorides: An alternative convenient biaryl synthesis<\/a>. Advanced Synthesis Catalysis 346(13-15), 1715-1727.<\/p>\n 13. Shan, Daxian ; Zheng, Ailian; Ballard, C. Eric; Wang, Wei;. Borchardt, Ronald T; Wang, Binghe (2000).\u00a0A facilitated cyclic ether formation and its potential application in solid-phase peptide and organic synthesis.<\/a>\u00a0Chemical Pharmaceutical Bulletin (2000), 48(2), 238-244.<\/p>\n 14. Sekine, Mitsuo; Yamada, Takeshi; Saneyoshi, Hisao; Seio, Kohji (2007). World Patent 2007\/102581.\u00a0Preparation of 2\u2032-Hydroxyl-Modified Ribonucleoside Derivative<\/a>. World Patent Office.<\/p>\n 15. Sharma, G. V. M.; Reddy, V. Goverdhan; Chander, A. Subhash; Reddy, K. Ravinder (2002)\u00a0Tetra-n-butylammonium fluoride: an efficient base for aza-Michael addition-synthesis of glycosyl b-amino acid esters<\/a>. Tetrahedron: Asymmetry 13(1), 21-24.<\/p>\n 16. Shiba, Yoshinobu (2007). World Patent 2007\/099896.\u00a0Method For Detaching Protecting Group On Nucleic Acid<\/a>.\u00a0 World Patent Office.<\/p>\n 17. Stawinski, Jacek; Stroemberg, Roger; Thelin, Mats; Westman, Erik (1988).\u00a0Studies on the t-butyldimethylsilyl group as 2\u2032-O-protection in oligoribonucleotide synthesis via the H-phosphonate approach<\/a>. Nucleic Acids Research 16(19), 9285-98.<\/p>\n\n
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\nTBAF\uc758 \uc885\ud569 \uc720\ud2f8\ub9ac\ud2f0\ubc31\uc11c \ub2e4\uc6b4\ub85c\ub4dc<\/a><\/p>\n
\nCAS# 87749-50-6
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\n[toggle title=”Click here for selected articles and patents on tetrabutylammonium fluoride.”]<\/p>\n